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The investment will make JD.com the second largest shareholder in Allianz China, said the insurance firm in a filing.
The deal will intensify the rivalry of their common backer Tencent Holdings with Alibaba Group.
The deal was brokered by Pony Ma, chief executive of Tencent Holdings, a backer of both companies.
The acquisition enlarges Alibaba’s food delivery empire, which includes delivery platform Koubei, as it competes with Meituan-Dianping.
Ofo claims it’s the largest investment garnered in a single round by a bike-sharing startup.
XtalPi uses AI, cloud computing and quantum physics to improve drug design processes.
The investment is Google’s second-ever in a Chinese startup.
The round values the firm at close to $50 billion and was joined by existing backer SoftBank.
The deal comes as Tencent pushes into retail, leveraging its relationship with JD.com and popular app WeChat.
The new center will join a list of similar ones operating in New York, Toronto, London and Zurich.